Operando Analysis of Semiconductor Junctions in Multi?Layered Photocathodes for Solar Water Splitting by Impedance Spectroscopy

نویسندگان

چکیده

Although electrochemical impedance spectroscopy (EIS) is a powerful technique for investigating optoelectronic devices, realistic equivalent circuit (EC) models suitable multi-layered water splitting electrodes have rarely been reported due to their complex nature. In the present study, utility of EIS method photocathodes photoelectrochemical demonstrated. By analyzing data TiO2-coated Sb2Se3 photocathodes, one able obtain information about constituent semiconductors and interfaces such as recombination processes, carrier lifetimes, doping densities, flat band potentials under operando conditions. The charge transfer time electrolyte also extracted from confirmed by transient photocurrent decay measurements. addition, successfully applied other with different classes light absorber, metal oxides (Cu2O) crystalline Si, compare device characteristics real operational It shown that lifetime photo-generated carriers in Si photocathode much higher than those Cu2O photocathodes. believed analysis presented this study will become routine characterization discovering limiting factors wide range photo-electrosynthetic well photovoltaic devices.

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ژورنال

عنوان ژورنال: Advanced Energy Materials

سال: 2021

ISSN: ['1614-6832', '1614-6840']

DOI: https://doi.org/10.1002/aenm.202003569